Tunnel electrode I. Electron transfer process at highly doped SnO2 electrode with Ce4+ in high overvoltage region.

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概要

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• Electron transfer theory at tunnel semiconductor electrode was derived from the double adiabatic perturbation theory. The cathodic current of Ce<SUP>4+</SUP> with very positive redox potential was measured at highly doped SnO<SUB>2</SUB> electrode. The rearrangement energy of 0.65 eV for Ce<SUP>4+</SUP> was estimated from the relationship of transfer coefficient <I>vs.</I> electrode potential. Large electron transfer rate in the high overvoltage region can be explained in terms of the contribution of excited vibrational states in the first coordination sphere into electron transfer.

• 公益社団法人 日本化学会の論文

著者

• Aikawa Yoshihiro

  Institute of Industrial Science, The University of Tokyo

• Kobayashi Kenkichiro

  Institute of Industrial Science, The University of Tokyo

• Sukigara Mitsunori

  Institute of Industrial Science, The University of Tokyo

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