The reaction of olefins with malonic acid in the presence of manganese(III) acetate.

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概要

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• The reaction of 1,1-diphenylethene with malonic acid in the presence of manganese(III) acetate gave 3,3,8,8-tetraphenyl-2,7-dioxaspiro[4.4]nonane-1,6-dione and 4,4-diphenyl-2-(2,2-diphenylethenyl)-4-butanolide. Similar reactions with 1,1-bis(4-methoxyphenyl)ethene, methylenecyclohexane, 2-phenylpropene, 1-octene, and cyclohexene yielded the corresponding 2,7-dioxaspiro[4.4]nonane-1,6-diones.

• 公益社団法人 日本化学会の論文

著者

• Ito Nobuyuki

  Department of Chemistry, Faculty of Science, Kumamoto University

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