Production of ethylene and propylene by the vapor-phase catalytic oxidative dehydrogenation of butane with carbonyl sulfide.
スポンサーリンク
概要
- 論文の詳細を見る
Ethylene and propylene were produced at high yields, additionally to butenes and butadiene, by the vapor-phase oxidative dehydrogenation of butane with COS over SiO<SUB>2</SUB>, Al<SUB>2</SUB>O<SUB>3</SUB>, MgO, and TiO<SUB>2</SUB> catalysts at 873–923 K. The results of kinetic and mechanistic studies indicate that ethylene and propylene are produced by the oxidative dehydrogenation through a homolytic mechanism followed by β-scission of the carbon–carbon bond.
著者
-
Sakatani Takashi
Department Of Pathology Graduate School Of Medicine
-
Akimoto Masamichi
Department Of Applied Chemistry And Biotechnology Faculty Of Engineering Niigata Institute Of Techno
-
Echigoya Etsuro
Department of Chemical Engineering, Tokyo Institute of Technology
関連論文
- Hydrothermal Dechlorination of a Raclaimed Oil in a Continuous Packed-Bed Reactor
- Primary non-Hodgkin's lymphoma of the breast treated nonsurgically : report of three cases
- CHLOROPLAST STRUCTURE AND SUB-CELLULAR DISTRIBUTION OF α-LINOLENIC ACID IN THE HOT-SPRING ALGA CYANIDIUM CALDARIUM
- CARBON DIOXIDE FIXATION AND α-LINOLENIC ACID PRODUCTION BY THE HOT-SPRING ALGA CYANIDIUM CALDARIUM
- Metabolism of L-Amino Acids in a Marine Bacterium Isolated from Mackerel Intestines in Relation to Eicosapentaenoic Acid Biosynthesis
- Thermal Liquefaction of Municipal Waste Plastics Pretreated with Supercritical Alkaline Alcohols
- Hydrothermal Refining of Fuel Oil Derived from Municipal Waste Plastics in a Continuous Packed-Bed Reactor
- Long-term clinical course of IgG4-related systemic disease accompanied by hypophysitis
- Behavior of the Nitrogen Atoms in Nylon, Polyurethane and ABS during Fuel Oil Production from Municipal Waste Plastics
- Fuel Oil Production from Municipal Waste Plastics Pretreated with Aqueous Alkaline Solutions
- Floating gallbladder strangulation caused by the lesser omentum : report of a case
- Preparation of solid catalysts for vapor-phase decomposition of carbonyl sulfide.
- Production of cyclohexene and reactive sulfur species in vapor-phase catalytic oxidative dehydrogenation of cyclohexane with carbonyl sulfide.
- Production of ethylene and propylene by the vapor-phase catalytic oxidative dehydrogenation of butane with carbonyl sulfide.
- Kinetic and mechanistic studies on the Koelbel-Engelhardt reaction over an iron oxide catalyst.
- Infrared studies of the isocyanate species formed in the reaction of NO with CO over Pt and Rh.
- Reaction mechanism of NO-NH3-O2 system,elucidated by transient response technique.
- Nature of oxygen species incorporated into acrylaldehyde in vapor-phase oxidation of propylene over supported copper catalyst.
- The effect of starting source on the concentration distribution of nickel supported on alumina.
- Determination of functional groups in glucose isomerase.
- TiO2-supported noble metal catalysts for the NO-CO and NO-CO-H2O-H2-O2 reactions.
- Estimation of bubble-to-liquid mass transfer rate coefficient by transient response technique and by steady state reaction studies.
- Carrier effect on the nature of V4+ and active oxygen species in vapor-phase oxidation of butadiene over supported divanadium pentaoxide catalysts.
- Kinetic evidence for the participation of a diatomic oxygen species in vapor-phase oxidation of butadiene over silver catalyst.
- Dehydration and Dehydrogenation of Alcohols over Acid-Base Bifunctional Catalysts
- Competition of the Two Reaction Mechanisms of Maleic Anhydride Formation in Vapor-Phase Oxidation of Butadiene over Supported Molybdena Catalysts
- Multicystic mesothelioma of the pericardium