Infrared studies of the isocyanate species formed in the reaction of NO with CO over Pt and Rh.
スポンサーリンク
概要
- 論文の詳細を見る
The behavior of isocyanates formed on the surface of Rh and Pt in the reaction of nitrogen oxide with carbon monoxide was studied by means of IR spectroscopy using a flow reactor. The isocyanate species readily reacted with N<SUB>2</SUB>O or H<SUB>2</SUB>O, however, it did not decompose when dosed with NO or CO. The catalytic activity of Pt–Al<SUB>2</SUB>O<SUB>3</SUB> in the reaction of NO+CO declined quickly with an increase in the amount of the surface isocyanate (–NCO). Accordingly, it is concluded that –NCO is not a reaction intermediate but an inhibitor of the reaction.
- 公益社団法人 日本化学会の論文
著者
-
Iida Hiroshi
Department of Cardiology, Tokuyama Central Hospital
-
Echigoya Etsuro
Department of Chemical Engineering, Tokyo Institute of Technology
-
Niiyama Hiroo
Department of Chemical Engineering and International Cooperation Center for Science and Technology, Tokyo Institute of Technology
-
Tanaka Motoo
Department of Chemical Engineering, Tokyo Institute of Technology
関連論文
- Evaluation of Left Atrial Function by the Functional Volume Change Curve Derived From Doppler Flow Spectra
- Adenosquamous carcinoma of the pancreas associated with humoral hypercalcemia of malignancy (HHM)
- Intima-media thickening of radial artery after transradial intervention (The examination by IVUS)
- Determinant Effecting Intimal Thickening of Radial Artery in Patients with Coronary Artery Disease : An IVUS Study
- Predictors of Intima-Media Thickening in the Radial Artery after Transradial Intervention : An IVUS Study
- SPERGEN-1 MIGHT BE AN ADHENSIVE MOLECULE ASSOCIATED WITH MITOCHONDRIA OF SPERMATOZOA(Developmental Biology)(Proceedings of the Seventy-Third Annual Meeting of the Zoological Society of Japan)
- IDENTIFICATION OF RAB12 AS A VESICLE-ASSOCIATED SMALL GTPASE HIGHLY EXPRESSED IN SERTOLI CELLS OF RAT TESTIS(Developmental Biology,Abstracts of papers presented at the 76^ Annual Meeting of the Zoological Society of Japan)
- IDENTIFICATION OF RAB12 AS A VESICLE-ASSOCIATED SMALL GTPase HIGHLY EXPRESSED IN SERTOLI CELLS OF RAT TESTIS(Developmental Biology,Abstracts of papers presented at the 75^ Annual Meeting of the Zoological Society of Japan)
- MOLECULAR CLONING OF RAT SPETEX-2 FAMILY GENES ENCODING A 23 KDA PROTEIN ASSOCIATED WITH THE PLASMA MEMBRANES OF HAPLOID SPERMATIDS(Developmental Biology,Abstracts of papers presented at the 75^ Annual Meeting of the Zoological Society of Japan)
- Improvement of Transient Vibration by Sensitivity Analysis
- EXPRESSION AND LOCALIZATION OF Rab6 AND Rab12 IN THE SEMINIFEROUS TUBULES OF RAT TESTIS(Developmental Biology)(Proceedings of the Seventy-Third Annual Meeting of the Zoological Society of Japan)
- A Surgical Case of Concomitant Aneurysms of the Brachiocephalic and Coronary Arteries
- PROFILE ANALYSES OF SPERGEN-2 EXPRESSED IN RAT TESTIS SPERMATOGENIC CELLS(Developmental Biology,Abstracts of papers presented at the 74^ Annual Meeting of the Zoological Society of Japan)
- SPERM STORAGE IN THE ISTHMUS OF THE MAMMALIAN OVIDUCT(Developmental Biology)(Proceedings of the Seventy-Third Annual Meeting of the Zoological Society of Japan)
- MATING-INDUCED CUMULUS-OOCYTE COMPLEXES MATURATION AND ROLE OF CUMULUS CELLS IN THE SUNCUS MURINUS(Developmental Biology)(Proceedings of the Seventy-Third Annual Meeting of the Zoological Society of Japan)
- cDNA CLONING OF A NOVEL GENE INVOLVED IN DIFFERENTIATION OF SPERMATOGENIC CELLS(Developmental Biology,Abstracts of papers presented at the 75^ Annual Meeting of the Zoological Society of Japan)
- HEAT SHOCK PROTEIN DNAJ HOMOLOGUE IS ASSOCIATED WITH IBA1(Developmental Biology,Abstracts of papers presented at the 75^ Annual Meeting of the Zoological Society of Japan)
- Endoscopic observation following aortic cusp plication
- EFFECTS OF BISPHENOL A ON CULTURED RAT SERTOLI CELLS(Developmental Biology)(Proceedings of the Seventy-Third Annual Meeting of the Zoological Society of Japan)
- Surgical repair of pectus excavatum
- cDNA CLONING OF SPERGEN-3 ENCODING A 75 KDA SPERMATID PROTEIN BEARING EF-HAND MOTIFS(Developmental Biology,Abstracts of papers presented at the 75^ Annual Meeting of the Zoological Society of Japan)
- A Porphyrin - Anchored Ultrathin Poly(vinylchloride) Film : Asymmetric Surface Property as Revealed by Interactions with 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone
- Preparation of solid catalysts for vapor-phase decomposition of carbonyl sulfide.
- Production of ethylene and propylene by the vapor-phase catalytic oxidative dehydrogenation of butane with carbonyl sulfide.
- Kinetic and mechanistic studies on the Koelbel-Engelhardt reaction over an iron oxide catalyst.
- Infrared studies of the isocyanate species formed in the reaction of NO with CO over Pt and Rh.
- Periodic operation effects in selective catalytic reduction of nitrogen monoxide with propane over alumina.
- Reaction mechanism of NO-NH3-O2 system,elucidated by transient response technique.
- Nature of oxygen species incorporated into acrylaldehyde in vapor-phase oxidation of propylene over supported copper catalyst.
- The effect of starting source on the concentration distribution of nickel supported on alumina.
- Hysteresis of catalytic activity in hydrogenation of ethylene on Ni/Al2O3.
- TiO2-supported noble metal catalysts for the NO-CO and NO-CO-H2O-H2-O2 reactions.
- Estimation of bubble-to-liquid mass transfer rate coefficient by transient response technique and by steady state reaction studies.
- Carrier effect on the nature of V4+ and active oxygen species in vapor-phase oxidation of butadiene over supported divanadium pentaoxide catalysts.
- Kinetic evidence for the participation of a diatomic oxygen species in vapor-phase oxidation of butadiene over silver catalyst.
- Dehydration and Dehydrogenation of Alcohols over Acid-Base Bifunctional Catalysts
- Competition of the Two Reaction Mechanisms of Maleic Anhydride Formation in Vapor-Phase Oxidation of Butadiene over Supported Molybdena Catalysts