Hydrogenation of 3-ethoxy-1-propene catalyzed by supported nickel catalysts.
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概要
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Nickel catalysts supported on different kinds of metal oxides were prepared to search for active catalysts for 3-ethoxy-1-propene hydrogenation. Ni/ThO<SUB>2</SUB> and Ni/SiO<SUB>2</SUB>–Al<SUB>2</SUB>O<SUB>3</SUB> catalysts exhibited high activity and selectivity for 1-ethoxypropane, while Ni/MgO, Ni/CaO, and Ni/La<SUB>2</SUB>O<SUB>3</SUB> catalysts preferentially catalyzed double bond migration to 1-ethoxy-1-propene which undergo hydrogenation with difficulty.
- 公益社団法人 日本化学会の論文
著者
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Hattori Hideshi
Department of Chemistry, Faculty of Science, Hokkaido University
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Matsuhashi Hiromi
Department of Chemistry, Faculty of Science, Hokkaido University
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