Oxidation of alcohols via alkoxymagnesium halides by an NAD+ model compound.
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概要
- 論文の詳細を見る
Alkoxymagnesium bromides prepared from phenylmagnesium bromide and alcohols are capable of reducing an NAD<SUP>+</SUP> model compound to the 1,4-dihydronicotinamide in good yields. The carbonyl products were detected in quantitative yields from diphenylmethanol and 1-phenylethanol but in low yields from benzyl alcohol and aliphatic alcohols. This is a new route to 1,4-dihydronicotinamides with alcohols although it remains uncertainty whether or not the route has relevance as a model process for NAD<SUP>+</SUP> oxidaiton of alcohols.
- 公益社団法人 日本化学会の論文
著者
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Shinkai Seiji
Department Of Applied Chemistry Faculty Of Engineering Kyushu University
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MANABE Osamu
Department of Applied Chemistry, Faculty of Engineering, Nagasaki University
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Era Hiroyuki
Department of Industrial Chemistry, Faculty of Engineering, Nagasaki University
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Tsuno Takaharu
Department of Industrial Chemistry, Faculty of Engineering, Nagasaki University
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