Determination of the vapor pressures of lithium chloride and sodium bromide by a molecular effusion-surface ionization method.
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By means of molecular effusion from a Knudsen cell and of thermal positive ionization on a glowing polycrystalline rhenium filament, the vapor pressure <I>P</I> (in atm) of LiCl or NaBr was measured as a function of cell temperature <I>T</I> (in K). The following equations were established empirically.<BR>log<SUB>10</SUB><I>P</I>(LiCl)=(7.948±0.102)−(10954±76)⁄<I>T</I> for 662–848 K,<BR>log<SUB>10</SUB><I>P</I>(NaBr)=(7.716±0.072)−(11138±55)⁄<I>T</I> for 669–882 K.
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