Alteration of reaction course in thermolysis of cis-diethylbis(tertiary phosphine)palladium(II) from reductive elimination to .BETA.-elimination process induced by addition of tertiary phosphine ligand.
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概要
- 論文の詳細を見る
Addition of tertiary phosphine to a solution containing <I>cis</I>-diethylbis(tertiary phosphine)palladium(II) alters thermolysis course of the complex from reductive elimination process liberating butane to β-hydrogen elimination process in which ethane and ethylene are released. Study with a deuterium-labeled ethyl complex indicates involvement of an internal metalation process.
- 公益社団法人 日本化学会の論文
著者
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Yamamoto Takakazu
Research Laboratory Of Resouces Utilization Tokyo Institute Of Technology
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Yamamoto Akio
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Ozawa Fumiyuki
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Kurihara Kunihiko
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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