A common factor determining the features of the photocatalytic hydrogenation and isomerization of alkenes over Ti-Si oxides.

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概要

• 論文の詳細を見る

• On addition of SiO<SUB>2</SUB> to TiO<SUB>2</SUB> photocatalysts, it has been found that the yields of C<SUB>2</SUB>H<SUB>6</SUB> and CH<SUB>4</SUB> in the photocatalytic hydrogenation of propylene as well as that of 1-butene in the photocatalytic isomerization of <I>cis</I>-2-butene decrease simultaneously. This gives some support for the mechanisms for both reactions where [Ti<SUP>3+</SUP>–O<SUP>−</SUP>] pairs are important.

• 公益社団法人 日本化学会の論文

著者

• Anpo Masakazu

  Department Of Applied Chemistry Colledge Of Engineering University Of Osaka Prefecture

• Kubokawa Yutaka

  Department of Applied Chemistry College of Engineering University of Osaka Prefecture

• Kodama Sukeya

  Department of Applied Chemistry, College of Engineering, University of Osaka Prefecture

• Nakaya Hiroaki

  Department of Applied Chemistry, University of Osaka Prefecture

関連論文

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• Photoluminescence Property of Titanium Silicalite-2 Catalyst and Its Photocatalytic Reactivity for the Direct Decomposition of NO at 295 K
• Stoichiometric Decomposition of Pure Water over Pt-Loaded Ti/B Binary Oxide under UV-Irradiation
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• The Photocatalytic Decomposition of Nitric Oxide on the Silver(I) Ion-exchanged ZSM-5 Catalyst
• Selective Dimerization and Hydrogenation of Ethylene on Active Zirconium Oxide with Coordinatively Unsaturated Surface Sites
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• Preparation, Characterization, and Reactivities of Highly Functional Titanium Oxide-Based Photocatalysts Able to Operate under UV-Visible Light Irradiation : Approaches in Realizing High Efficiency in the Use of Visible Light
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• Phosphorescence and Photochemical Properties of Benzophenone Adsorbed on Alkali Cations-Exchanged Zeolite
• Fluorescence Properties of BDD Molecules Doped in Si-Ti Binary Oxide Systems by the Sol-Gel Method
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• Reactions of NH radicals. V. Photolysis of HN3 in the presence of C3H8 at 313 nm.
• Reactions of NH radicals. III. Photolysis of HN3 in the presence of C2H4 at 313nm.
• Photocatalytic isomerization of butenes over ZnO and SnO2.
• Oxidation of propylene adsorbed on metal oxides. Oxygen species in catalytic oxidation.
• Photophysics on solid surface. Time-resolved fluorescence spectra of pyrene adsorbed on calcinated Vycor glass.
• The nature of oxygen species responsible for propene oxidation over V-Mo and V-Sn oxides.
• Photocatalysis on native and platinum-loaded TiO2 and ZnO catalysts. Origin of different reactivities on wet and dry metal oxides.
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• Catalytic activity of V-Sn oxides for oxidation reactions.
• Photolyses of Aliphatic Ketones Adsorbed on Porous Vycor Glass
• Infrared study of the oxidation of 2-propanol on TiO2.
• Infrared studies of the oxidation of 2-propanol on ZnO.
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• Oxidation of Propylene Adsorbed on Oxide Catalysts
• Reactions in the Adsorbed Layer: Hydrogenation of Acetone on Nickel Catalysts
• Reactivity of excited triplet alkyl ketones in solution. I. Quenching and hydrogen abstraction of triplet acetone.
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