Oxidation of propylene adsorbed on metal oxides. Oxygen species in catalytic oxidation.
スポンサーリンク
概要
- 論文の詳細を見る
Adsorption of ethylene and propylene has been investigated volumetrically with various oxide catalysts. From the results together with those of oxidation of propylene adsorbed on oxides, it is concluded that the difference between the characteristics of oxidation of propylene adsorbed on the oxide catalysts for complete or selective oxidation is attributable to the difference in the oxygen species responsible for oxidation rather than that in the adsorbed state of propylene. A comparison of characteristics of the oxidation of adsorbed propylene in the presence of gaseous oxygen and in a vacuum suggests that on the catalysts for complete oxidation, adsorbed oxygen plays a significant role in the oxidation because of its higher activity as compared to that of lattice oxygen.
- 公益社団法人 日本化学会の論文
著者
-
Ono Takehiko
Department of Applied Chemistry, University of Osaka Prefecture
-
Ono Takehiko
Department Of Applied Chemistry Graduate School Of Engineering Osaka Prefecture University
-
Kubokawa Yutaka
Department of Applied Chemistry College of Engineering University of Osaka Prefecture
-
Kubokawa Yutaka
Department of Applied Chemistry, University of Osaka Prefecture
関連論文
- FT-IR Study of Structure of Toluene Adsorbed on Vanadium-Titanium Oxide
- Characterization of Fe - Oxide Species Prepared onto ZSM - 5 Zeolites and Their Role in the Photocatalytic Decomposition of N_2O into N_2 and O_2
- FT-IR Study of Oxidation Mechanism of 2-Butene on Vanadium Oxide Layered on ZrO_2
- Investigation of Chemisorption by Desorption Rate Measurement; CO2 on ZnO and NiO; CO on NiO
- Rate of Desorption from a Heterogeneous Surface
- Catalytic activity of MoO3 and V2O5 highly dispersed on TiO2 for oxidation reactions.
- Photocatalytic isomerization of butenes over TiO2. Photo-formed active species and characteristics of reaction.
- Photocatalyzed isomerization of butenes over metal sulfides. High photocatalytic activity and its origin.
- Photocatalytic isomerization of butenes over ZnO and SnO2.
- Oxidation of propylene adsorbed on metal oxides. Oxygen species in catalytic oxidation.
- The nature of oxygen species responsible for propene oxidation over V-Mo and V-Sn oxides.
- Photochemistry in the Adsorbed Layer. V. Effects of Surface Pretreatments upon the Photolysis of Adsorbed 2-Pentanone
- Catalytic activity of V-Sn oxides for oxidation reactions.
- Photolyses of Aliphatic Ketones Adsorbed on Porous Vycor Glass
- Infrared study of the oxidation of 2-propanol on TiO2.
- Infrared studies of the oxidation of 2-propanol on ZnO.
- A common factor determining the features of the photocatalytic hydrogenation and isomerization of alkenes over Ti-Si oxides.
- Oxidation of Propylene Adsorbed on Oxide Catalysts
- Reactions in the Adsorbed Layer: Hydrogenation of Acetone on Nickel Catalysts
- Reactivity of excited triplet alkyl ketones in solution. I. Quenching and hydrogen abstraction of triplet acetone.
- Photochemistry in the adsorbed layer. VIII. Lifetimes of excited alkyl ketones and alkyl radicals adsorbed on porous Vycor glass.