Hydrogenation of carbon monoxide to form light olefins over an iron-modified crystalline silica.

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概要

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• Iron-modified crystalline silicas prepared from an Fe(II) compound were more active than those prepared from an Fe(III) compound. The (C<SUB>2</SUB>H<SUB>4</SUB>+C<SUB>3</SUB>H<SUB>6</SUB>) selectivity of the former was lower than that of the latter. By the addition of alkaline earth metals, the (C<SUB>2</SUB>H<SUB>4</SUB>+C<SUB>3</SUB>H<SUB>6</SUB>) selectivity of the catalysts prepared from the Fe(II) compound increased remarkably.

• 公益社団法人 日本化学会の論文

著者

• Okado Hideo

  Maruzen Petrochemical Co., Ltd.

• Takaya Haruo

  Catalysis Division, National Chemical Laboratory for Industry

• Hagiwara Hiroyuki

  Catalysis Division, National Chemical Laboratory for Industry

• Yanagisawa Hiroshi

  Ube Industries Co., Ltd.

• Okabe Kiyomi

  Catalysis Division, National Chemical Laboratory for Industry

• Sano Tsuneji

  Catalysis Division, National Chemical Laboratory for Industry

• Yasumoto Yoshiroh

  Catalysis Division, National Chemical Laboratory for Industry

関連論文

• The steam stability of H-ZSM-5-type zeolites containing alkaline earth metals.
• The migration of barium into zeolite channels from the outer surfaces of zeolite crystals.
• Olefin hydrogenation over ZSM-5 type zeolite catalysts modified with alkaline earth metals.
• Hydrogenation of carbon monoxide to form light olefins over an iron-modified crystalline silica.
• The long-term testing of ZSM-5-type zeolite containing strontium for the high-temperature conversion of methanol to olefin.

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