Synthesis and properties of a new photoresponsive crown ether with a fluorescent stilbene-cap.
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概要
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A new photoresponsive crown ether <B>2</B> with a stilbene-cap was synthesized. The crown <I>trans</I>-<B>2</B> could extract Li<SUP>+</SUP> and Na<SUP>+</SUP> into the organic phase, and UV light irradiation which produces photoisomerized <I>cis</I>-<B>2</B> enhanced the extractability. Thus, the stilbene-cap induces the conformational change in the crown ether moiety by photoirradiation.
- 公益社団法人 日本化学会の論文
著者
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Shinkai Seiji
Department Of Applied Chemistry Faculty Of Engineering Kyushu University
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Miyazaki Kiminori
Department Of Biochemistry Kumamoto University School Of Medicine
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MANABE Osamu
Department of Applied Chemistry, Faculty of Engineering, Nagasaki University
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Nakashima Mikio
Department of Anesthesiology, Saga Medical School
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Manabe Osamu
Department of Industrial Chemistry, Faculty of Engineering, Nagasaki University
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