Synthesis and structure of (nitroacetato)((7RS,14RS)-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II), (Ni(na)(Me6(14)aneN4)).
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概要
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The title compound, [Ni(na)(Ma<SUB>6</SUB>[14]aneN<SUB>4</SUB>)], has been synthesized by the reaction of α-[Ni(Me<SUB>6</SUB>[14]aneN<SUB>4</SUB>)](ClO<SUB>4</SUB>)<SUB>2</SUB> with potassium nitroacetate (K<SUB>2</SUB>na) in water. X-Ray analysis shows that the complex is a <I>cis</I>-NiO<SUB>2</SUB>N<SUB>4</SUB> type with the tetraazamacrocycle folded, and that a dianionic nitroacetate (na<SUP>2−</SUP>) chelates the nickel(II) with one oxygen atom of the CO<SUB>2<SUP>−</SUP></SUB> moiety and one oxygen atom of the NO<SUB>2<SUP>−</SUP></SUB> moiety to form a six membered chelate ring.
- 公益社団法人 日本化学会の論文
著者
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Ito Tasuku
Department of Applied Molecular Science, Institute for Molecular Science
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Ito Haruko
Department of Applied Molecular Science, Institute for Molecular Science, Okazaki National Research Institutes
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Ito Haruko
Department of Applied Molecular Science, Institute for Molecular Science
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