Cerium or ruthenium catalyzed oxidation of alcohols to carbonyl compounds by means of sodium bromate.

スポンサーリンク

概要

• 論文の詳細を見る

• Sodium bromate has been found to be effective oxidant for oxidation of alcohols in the presence of cerium or ruthenium compounds in biphase reaction. Selective oxidation of secondary alcohols was performed in the presence of primary ones using cerium(IV) ammonium nitrate (CAN) or cerium(IV) sulfate (CS) as catalyst. For instance, treatment of 1,10-undecanediol with CS/NaBrO<SUB>3</SUB> provided 11-hydroxy-2-undecanone in 82% yield. Ruthenium catalyzed biphase oxidation of alcohols with sodium bromate provided the corresponding aldehydes or ketones in good to excellent yields.

• 公益社団法人 日本化学会の論文

著者

• Kanemoto Shigekazu

  Department of Industrial Chemistry, Faculty of Engineering, Kyoto University

関連論文

• Cerium or ruthenium catalyzed oxidation of alcohols to carbonyl compounds by means of sodium bromate.
• Rearrangement of vic-diol monoacetates promoted by organoaluminium compounds.
• Chromium(VI) or ruthenium(II) complex catalysis in oxidation of alcohols to aldehydes and ketones by means of bis(trimethylsilyl) peroxide.
• Cr(III) or Ce(IV) impregnated perfluorinated resin-sulfonic acid catalyst for the oxidation of alcohols.

スポンサーリンク