Stereoselective synthesis of allyl- or alkynyl-substituted (Z)-vinylsilanes via organoboranes.
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概要
- 論文の詳細を見る
Copper(I) iodide-catalyzed cross-coupling reactions of (<I>Z</I>)-(1-trimethylsilyl-1-alkenyl)dicyclohexylboranes with allyl bromide or 1-bromo-1-hexyne gave stereoselectively (<I>Z</I>)-1,4-dienes or conjugated (<I>Z</I>)-enynes having a trimethylsilyl group on the internal carbon atom of the double bond.
- 公益社団法人 日本化学会の論文
著者
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Masuda Yuzuru
Department Of Industrial Chemistry Kitami Institute Of Technology
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Arase Akira
Department Of Industrial Chemistry Kitami Institute Of Technology
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Hoshi Masayuki
Department of Applied Chemistry, Kitami Institute of Technology
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