The selective elimination of secondary alkyl group from trialkylborane by the successive treatments with anisole and dimethyl sulfoxide. A supply of the synthetic intermediate for primary alkyl derivatives.
スポンサーリンク
概要
- 論文の詳細を見る
Secondary alkyl group of trialkylborane, derived from terminal olefin and borane, was selectively eliminated by the successive treatments with anisole and dimethyl sulfoxide. By the use of the resulting trialkylborane as the synthetic intermediate for primary alkyl derivatives, the contaminations of secondary alkyl derivatives were greatly reduced.
- 公益社団法人 日本化学会の論文
著者
-
Masuda Yuzuru
Department Of Industrial Chemistry Kitami Institute Of Technology
-
Hoshi Masayuki
Department of Applied Chemistry, Kitami Institute of Technology
-
Arase Akira
Department of Applied Chemistry, Kitami Institute of Technology
関連論文
- Preparation of Poly(t-butyl methacrylate)-Polyimide Particles by Dispersion Polymerization of t-Butyl Methacrylate Using Poly(amic acid) as a Stabilizer and Subsequent Imidization
- Platinum-catalyzed Aromatic C-H Silylation of Arenes with 1,1,1,3,5,5,5-Heptamethyltrisiloxane
- Aromatic C-H Borylation Catalyzed by Hydrotris(pyrazolyl)borate Complexes of Rhodium and Iridium
- Preparation of Polystyrene-Polyimide Particles by Dispersion Polymerization of Styrene Using Poly(amic acid) as a Stabilizer
- Synthesis of Polymer Microspheres with Mercapto Groups by Polycondensation of 1,3-Propanedithiol and 1,6-Dibromohexane in the Presence of a Poly[styrene-alkylacrylamide] Latex
- Rhodium-and Ruthenium-Catalyzed Dehydrogenative Borylation of Vinylarenes with Pinacolborane : Stereoselective Synthesis of Vinylboronates
- Ready Preparation of Trialkoxyboranes and Dialkoxyboranes by LiBEt_3H-Promoted Reaction of BH_3 in Tetrahydrofuran with Alcohols
- Stereoselective synthesis of allyl- or alkynyl-substituted (Z)-vinylsilanes via organoboranes.
- The reaction of cis-1,2-dichloroethylene with borane in tetrahydrofuran. The supply of monochloroborane in a tetrahydrofuran solution.
- Bis(acetylacetonato)copper catalyzed cross-coupling reaction of alkenyldicyclohexylborane with 1-bromo-1-alkyne or 3-bromo-1-propene.
- A novel synthesis of internal alkenyldialkylborane by the reaction of 1-halo-1-alkenyldialkylborane with Grignard reagent.
- The hydroboration of 1-alkylthio-1-alkynes, and its application to the syntheses of S-alkyl alkanethioates and (Z)-1-alkylthio-1-alkenes.
- An improved method for stereoselective synthesis of (E-alkenes via alkenyldialkylboranes)
- The selective elimination of secondary alkyl group from trialkylborane by the successive treatments with anisole and dimethyl sulfoxide. A supply of the synthetic intermediate for primary alkyl derivatives.
- The reactions of (1-halo-1-alkenyl)dialkylboranes with lead(IV) acetate or (diacetoxyiodo)benzene. A stereoselective synthesis of 1-halo-1,2-dialkylethylenes.