In situ X-ray observation on the intercalation of weak interaction molecules into Perovskite-type layered crystals (C9H19NH3)2PbI4 and (C10H21NH3)2CdCl4.
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概要
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The intercalation-deintercalation process of weak interaction organic molecules such as 1-chloronaphthalene and <I>o</I>-dichlorobenzene into highly oriented polycrystalline (C<SUB>10</SUB>H<SUB>21</SUB>NH<SUB>3</SUB>)<SUB>2</SUB>CdCl<SUB>4</SUB> films and hexane into (C<SUB>9</SUB>H<SUB>19</SUB>NH<SUB>3</SUB>)<SUB>2</SUB>Pbl<SUB>4</SUB> single crystals has been observed in situ by using X-ray technique. The process is highly reversible. Increasing of interlayer spacing is in reasonable agreement with the size of the intercalated molecules and corresponds to the parallel orientation of aromatic ring planes or hexane chains in between two paraffin layers of the host crystals.
- 公益社団法人 日本化学会の論文
著者
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Inabe Tamotsu
Department Of Chemistry Faculty Of Science Hokkaido University
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Maruyama Yusei
Department of Chemistry Faculty of science The University of Tokyo
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Inabe Tamotsu
Department of Molecular Assemblies, Institute for Molecular Science
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Dolzhenko Yuri
Department of Physical Chemistry, Kharkov Polytechnical Institute
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