Hydrogenation and dimerization of bicyclo(2.2.1)hepta-2,5-diene catalyzed by cobalt(I) complexes.
スポンサーリンク
概要
- 論文の詳細を見る
Bicyclo[2.2.1]hepta-2,5-diene <B>1</B> was hydrogenated to bicyclo[2.2.1]hept-2-ene <B>2</B> and tricyclo[2.2.1.0<SUP>2,6</SUP>]heptane <B>3</B> in a 70:30 ratio and dimerized to Binor-S <B>4</B> by [CoX(PPh<SUB>3</SUB>)<SUB>3</SUB>]–BF<SUB>3</SUB>·Et<SUB>2</SUB>O catalysts (X=halogen). <B>1</B> was dimerized to <B>4–7</B> having tricyclo[2.2.1.0<SUP>2,6</SUP>]heptane skeletons by a [Co(SCN)(PPh<SUB>3</SUB>)<SUB>3</SUB>]–ZnBr<SUB>2</SUB>–Zn system in THF.
- 公益社団法人 日本化学会の論文
著者
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Kanai Hiroyoshi
Department Of Cardiovascular Medicine Gunma University Graduate School Of Medicine
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Kanai Hiroyoshi
Department of Hydrocarbon Chemistry and Division of Molecular Engineering, Faculty of Engineering, Kyoto University
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Watabe Yoshiyuki
Department of Hydrocarbon Chemistry and Division of Molecular Engineering, Faculty of Engineering, Kyoto University
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Nakayama Taisei
Department of Hydrocarbon Chemistry and Division of Molecular Engineering, Faculty of Engineering, Kyoto University
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