Resonance Raman spectra of red-shifted retinal Schiff's base.
スポンサーリンク
概要
- 論文の詳細を見る
We have found that the visible absorption maximum (λ<SUB>max</SUB>) of retinal Schiff's base in fluoro alcohols is considerably red-shifted. The C=N stretching Raman line exhibits a frequency shift in deuterated fluoro alcohols, indicating that the Schiff's base is protonated. Frequencies of the in-phase C=C stretching Raman lines (ν<SUB>C=C</SUB>) changed linearly with λ<SUB>max</SUB>, and the ν<SUB>C=C</SUB> vs. λ<SUB>max</SUB> correlation coincides with that observed for retinoid proteins.
- 公益社団法人 日本化学会の論文
著者
-
Kitagawa Teizo
Instisute For Molecular Science Okazaki National Research Institutes
-
Sugihara Toshiharu
Department of Home Economics, Gifu University
関連論文
- C-H Activation by Cu(III)_2O_2 Intermediate with Secondary Amino Ligand
- Effects of Concerted Hydrogen Bonding of Distal Histidine on Active Site Structures of Horseradish Peroxidase ; Resonance Raman Studies with Asn-70 Mutants
- Modulation of the Copper-Dioxygen Reactivity by Stereochemical Effect of Tetradentate Tripodal Ligands
- (μ-Alkoxo)diiron(II,II) Complexes of N, N, N', N'-Tetrakis(2-(6-methylpyridyl)methyl)-1, 3-diaminopropane-2-olate and the Reversible Formation of the O_2-Adducts
- Raman Spectroscopic Observations of Anomalous Conformational Behavior of Short Poly(oxyethylene) Chains in Water
- A Superoxodicopper(II)Complex Oxidatively Generated by a Reaction of Di-μ-hydroxodicopper(II)Complex with Hydrogen Peroxide
- Time-Resolved Resonance Raman Investigation of Cytochrome Oxidase Catalysis: Observation of a New Oxygen-Isotope Sensitive Raman Band.
- Frequency Distribution, Specific Heat, and Young's Moduli of Orthorhombic Polyethylene with Skeletal Approximation
- Resonance Raman Study on Photoreduction of Iron-Porphyrins. A Novel Insight into the Ligand-Aided Process.
- The Raman Spectra and Molecular Conformations of Surfactants in Aqueous Solution and Crystalline States
- Tautomeric equilibrium of salicylidene Schiff base. UV-visible absorption and Raman spectroscopic studies.
- Accordionlike skeletal motions of CH3NHCONH(CH2)nCH3(n=1-15).
- Resonance Raman spectra of red-shifted retinal Schiff's base.
- Resonance Raman evidence for the presence of the FeIV=O bond in horseradish peroxidase compound II.
- Raman Spectra and Internal Rotation of Ethyl Methyl Ether
- The Raman Spectra of Surfactants and The Concentration Dependence of Their Molecular Conformations in Aqueous Solutions