Tautomeric equilibrium of salicylidene Schiff base. UV-visible absorption and Raman spectroscopic studies.
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概要
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The solvent effect and temperature dependence on the Raman and absorption spectra demonstrated the existence of a tautomeric equilibrium for the title compound between the enol form and the protonated Schiff base form in methanol; the latter form is more stable by ca. 850 cal mol<SUP>−1</SUP>(1 cal=4.184 J) than the former. Characteristic Raman bands for the two tautomers have been identified.
- 公益社団法人 日本化学会の論文
著者
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Kitagawa Teizo
Instisute For Molecular Science Okazaki National Research Institutes
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KITAGAWA Teizo
Institute for Molecular Science, Okazaki National Research Institutes
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Lee Ho-hi
Institute for Molecular Science, Okazaki National Research Institutes
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