Synthesis and photolysis of tricyclo(5.3.1.02,6)undeca-3,9-dien-8-ones and -4,9-dien-8-ones. Formation of novel trishomocubanones.

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概要

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• A series of 10-substituted tricyclo[5.3.1.0<SUP>2,6</SUP>]undeca-3,9-dien-8-ones (<B>6</B>) and the 4,9-dien-8-one isomers (<B>7</B>) were synthesized and photolyzed. Upon irradation, whereas most of the derivatives underwent [2+2] photocyclization to give the corresponding novel trishomocubanones, the methyl and phenyl derivatives of <B>7</B> afforded products attributable to intramolecular hydrogen abstraction by the β-carbon of the α,β-unsaturated ketone along with the photocyclization products.

• 公益社団法人 日本化学会の論文

著者

• Ogino Toshio

  Department Of Electrical And Computer Engineering Yokohama National University

• Awano Kazuyuki

  Department of Industrial Chemistry, Nagaoka Technical College

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• Synthesis and photolysis of tricyclo(5.3.1.02,6)undeca-3,9-dien-8-ones and -4,9-dien-8-ones. Formation of novel trishomocubanones.

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