Synthesis of 2,6-dimethyl-6-(8-methyl-4-methylene-7-nonenyl)-2-cyclohexene-1-methanols from .ALPHA.-santonin.
スポンサーリンク
概要
- 論文の詳細を見る
α-Santonin was converted to 2,6-dimethyl-6-(8-methyl-4-methylene-7-nonenyl)-2-cyclohexene-1-methanols (<B>1a</B> and <B>1b</B>). Both spectral data of <B>1a</B> and <B>1b</B> were found to be different from those reported for magydar-2,10(20),13-trien-17-ol, a diterpene isolated from <I>Magydaris panacifolia</I> (Vahl) Lange. This indicates that the structure of the natural diterpene should be revised; the structure was later revised to <I>t</I>-6-hydroxymethyl-1, <I>t</I>-3-dimethyl-<I>t</I>-2-(3-methyl-2-butenyl)-3-(4-methyl-3-pentenyl)-<I>r</I>-1-cyclohexanol.
- 公益社団法人 日本化学会の論文
著者
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Matsuo Yukiko
Department Of Chemistry Graduate School Of Science Osaka University
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Masunaga Yukari
Departments Of Medication Use Analysis And Clinical Research " Pharmacotherapy B Biopharmaceuti
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Nagano Hajime
Department Of Chemistry Faculty Of Science Ochanomizu University
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Matsuo Yukiko
Department of Chemistry, Faculty of Science, Ochanomizu University
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Shiota Michio
Department of Chemistry, Faculty of Science, Ochanomizu University
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Masunaga Yukari
Department of Chemistry, Faculty of Science, Ochanomizu University
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