Stereoselective syntheses of 1,3,5-trihydroxy-2,4-dimethylpentane equivalents from methyl .ALPHA.-mannopyranosides.
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概要
- 論文の詳細を見る
The optically active 1,3,5-trihydroxy-2,4-dimethylpentane equivalents: methyl 2,4-dideoxy-2,4-di-<I>C</I>-methyl-α-D-ido- and talopyranosides and their enantiomers, which should be suitable for the syntheses of propionate-derived natural products, were stereo- and regioselectively prepared from methyl α-D- and L-mannopyranosides through the reactions of the 3,4-anhydro-2-<I>O</I>-mesyl- and 3,4-anhydro-2-<I>C</I>-methylaltropyranoside derivatives with methylmagnesium bromide and methylmagnesium chloride.
- 公益社団法人 日本化学会の論文
著者
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Tatsuta Kuniaki
Department Of Applied Chemistry Faculty Of Science And Technology Keito University
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Koguchi Yoshihito
Department Of Applied Chemistry Keio University Hiyoshi
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Tatsuta Kuniaki
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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Kase Motohiro
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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