Stereoselective syntheses of 2-deoxy-.BETA.-C-arabino- and ribopyranosides: 2-Deoxy-.BETA.-arabino- and ribopyranosyl cyanides.
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概要
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2-Deoxy-β-arabino- and ribopyranosyl cyanides, which should be suitable for the syntheses of biologically active products, were stereoselectively prepared from the reaction of the enones, 1,5-anhydro-2-deoxy-<I>erythro</I>-hex-1-en-3-ulose derivatives, with acetone cyanohydrin, followed by the stereoselective reduction of the producing ketones with NaBH<SUB>4</SUB>–CeCl<SUB>3</SUB>·7H<SUB>2</SUB>O and L-Selectride, respectively.
- 公益社団法人 日本化学会の論文
著者
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Hayakawa Jun
Department Of Anesthesia Kanagawa Cancer Center Hospital
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Tatsuta Kuniaki
Department Of Applied Chemistry Faculty Of Science And Technology Keito University
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Tatsuzawa Yukio
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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Hayakawa Jun
Department of Applied Chemistry, Faculty of Science and Technology, Keio University
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