Studies on ferrocene derivatives. V. Oxidation reaction of (o-substituted phenyl)ferrocenes.
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概要
- 論文の詳細を見る
The oxidation reactivity of (<I>o</I>-substituted phenyl)ferrocenes with air was measured in acidic solution. The reactivity of <I>o</I>-acetyl, <I>o</I>-methoxycarbonyl, and <I>o</I>-methoxy derivatives was higher than that of the corresponding <I>p</I>-isomers. On the other hand, for <I>o</I>-hydroxy and omethyl derivatives, the reactivity was lower than that of <I>p</I>-isomers. It was considered that the reactivity of <I>o</I>-isomers is influenced by the coordination ability of proton to iron atom. The coordination ability is governed by both the I-effect and steric effect of substituent.
- 公益社団法人 日本化学会の論文
著者
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Hayashi Takatoshi
Department Of Applied Chemistry Faculty Of Science And Engineering Ritsumeikan University
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Okada Yutaka
Department Of Applied Chemistry Faculty Of Science And Engineering Ritsumeikan University
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Yamamoto Noriyuki
Department of Chemistry, Faculty of Science and Engineering, Ritsumeikan University
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