Studies on ferrocene derivatives. VII. Solvent effect on the oxidation reaction of t-butylferrocenes.
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概要
- 論文の詳細を見る
The oxidation reactivity of <I>t</I>-butylferrocenes with air was measured in 1,2-dichloroethane or 1,4-dioxane. Their reactivity in 1,2-dichloroethane was increased with increasing the number of the substituents. It was considered that the oxidation proceeds through air oxidation with catalytic proton. On the other hand, in 1,4-dioxane, the conversion amount to oxidized form of ferrocene or <I>t</I>-butylferrocene suddenly incresed in the course of the reaction. In this solvent, the ferrocene nucleus was decomposed to give Fe<SUP>3+</SUP> ion. It seems that the substrate was oxidized by Fe<SUP>3+</SUP> ion formed.
- 公益社団法人 日本化学会の論文
著者
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Hayashi Takatoshi
Department Of Applied Chemistry Faculty Of Science And Engineering Ritsumeikan University
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Okada Yutaka
Department Of Applied Chemistry Faculty Of Science And Engineering Ritsumeikan University
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Hayashi Takatoshi
Department of Chemistry, Faculty of Science and Engineering, Ritsumeikan University
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Yamashita Tetsurou
Department of Chemistry, Faculty of Science and Engineering, Ritsumeikan University
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