Electronic conduction in solid nitrobenzene containing nitrobenzene anion radical and tetrabutylammonium perchlorate.
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The electric conductivities of frozen nitrobenzene containing various amount of tetrabutylammonium perchlorate and nitrobenzene anion radical were measured. The conductivity increased markedly with the concentration of the nitrobenzene anion radical. The mechanism of the electric conduction of the nitrobenzene is discussed and it is concluded that at low concentration of anion radical the increase of the electric conductivity is due to electronic conduction by a hopping mechanism. The rate constant of electron transfer (hopping) between any nearest neighbored sites is about 10<SUP>5</SUP> s<SUP>−1</SUP> at −15 °C, which is smaller by 2 orders than that in hypothetical liquid nitrobenzene at the same temperature.
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