Stereospecific preparation of chiral 1,5-diketone by one-methylene incorporated dimerization reaction of d-camphor enolate and reduction of the 1,5-diketone.

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概要

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• The reaction of <I>d</I>-camphor with <I>N</I>,<I>N</I>-dimethylformamide (DMF) in the presence of potassium hydride stereoselectively gave bis[(1<I>R</I>,3<I>S</I>,4<I>R</I>)-2-oxo-3-bornyl]methane (<B>1</B>). This new condensation reaction is proposed to proceed by an attack of the <I>d</I>-camphor enolate to DMF and a subsequent reduction. Three chiral diols were obtained from the reduction of <B>1</B>.

• 公益社団法人 日本化学会の論文

著者

• Yamamoto Akihisa

  Department of Chemistry, Kochi University

関連論文

• The ^C(p, p'3α)Breakup Reaction Induced by 14, 18 and 26 MeV Protons
• Stereospecific preparation of chiral 1,5-diketone by one-methylene incorporated dimerization reaction of d-camphor enolate and reduction of the 1,5-diketone.

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