The removal of nitrogen monoxide by the dry iron(II) complex immobilized on chelate resin. The preparation and characterization of the complex.
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概要
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A new dry-type adsorbent for nitrogen monoxide was successfully prepared from an iron(II) salt and a chelate resin containing iminodiacetic acid moieties. The capability of adsorbing nitrogen monoxide depended greatly on the method of preparation. The very active adsorbent was prepared by mixing 31.4 mmol of iron(II) sulfate and a commercial chelate resin containing 21.0 mmol of iminodiacetic acid moieties; the mixture was dried after the solid parts had been washed with methanol. The resulting solid adsorbent could adsorb more than 99% of the nitrogen monoxide from 6 dm<SUP>3</SUP> of nitrogen gas containing 1000 ppm of nitrogen monoxide within 25 min. This high capability for adsorbing nitrogen monoxide was derived from the increase in the surface area (43.1 m<SUP>2</SUP> g<SUP>−1</SUP>) of the resin-immobilized iron(II) complex upon washing with methanol. The mechanism for the increase in the surface area is also discussed.
- 公益社団法人 日本化学会の論文
著者
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Asanuma Hiroyuki
Department Of Chemistry And Biotechnology Graduate School Of Engineering The University Of Tokyo
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Toshima Naoki
Department Of Applied Chemistry
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Hirai Hidefumi
Department Of Industrial Chemistry Faculty Of Engineering Science University Of Tokyo
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Asanuma Hiroyuki
Department of Industrial Chemistry, Faculty of Engineering, The University of Tokyo
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