Nickel-catalyzed dehydrogenation of amines to nitriles.

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概要

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• Aliphatic primary amines having α-methylene underwent oxidative dehydrogenation on treatment with NiSO<SUB>4</SUB> as a catalyst and K<SUB>2</SUB>S<SUB>2</SUB>O<SUB>8</SUB> as an oxidant to give the corresponding nitriles in good yields. Benzhydrylamine was converted to benzhydrylideneamine quantitatively under the same reaction conditions.

• 公益社団法人 日本化学会の論文

著者

• YAMAZAKI Shigekazu

  Toyama Industrial Technology Center

• Yamazaki Yasuyuki

  Toyama Industrial Technology Center

関連論文

• Development of SnO_2-based Gas Sensors for Detection of Volatile Organic Compounds
• Oxidation of Benzaldehydes Catalyzed by Methyltrioxorhenium with Hydrogen Peroxide
• Oxidation of Secondary Amines with NiSO_4-K_2S_2O_8
• Selective Synthesis of Sulfoxides and Sulfones by Methyltrioxorhenium-Catalyzed Oxidation of Sulfides with Hydrogen Peroxide
• Methyltrioxorhenium-Catalyzed Oxidation of Secondary and Primary Amines with Hydrogen Peroxide
• Nickel-catalyzed dehydrogenation of amines to nitriles.

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