Substituent effects on the electronic absorption and MCD spectra of five- and six-coordinate nitrosyl(tetraphenylporphyrinato)iron(II) complexes.
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Electronic absorption and MCD spectra of five- and six-coordinate nitrosyl iron(II) complexes of a series of tetrakis(para-substituted phenyl)porphyrins have been investigated in order to elucidate the cis-effect of para-substituents. The MCD spectroscopy was more sensitive to the substituent effect than the electronic absorption spectroscopy.
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