Conversion of hydroxyl groups in alcohols to other functional groups witn N-hydroxy-2-thiopyridone, and its application to dialkylamines and thiols.
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概要
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The radical decarboxylation reaction of <I>N</I>-alkoxyoxalyloxy-2-thiopyridone which was prepared by the reaction of alcohol, oxalyl chloride, and <I>N</I>-hydroxy-2-thiopyridone was studied both in the absence and presence of olefinic compounds. The same reactions with olefinic and acetylenic alcohols gave the corresponding lactone derivatives. On the other hand the unsymmetrical alkyl 2-pyridyl disulfides were obtained by the same reaction with aliphatic thiols.
- 公益社団法人 日本化学会の論文
著者
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Togo Hideo
Department Of Chemistry Faculty Of Science Chiba University
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YOKOYAMA MASATAKA
Department of Anatomy, Jikei University School of Medicine
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Fujii Misa
Department of Chemistry, Faculty of Science, Chiba University
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