Redox reaction of aromatic aldehydes with Fe3(CO)12.
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概要
- 論文の詳細を見る
Aromatic aldehydes react with Fe<SUB>3</SUB>(CO)<SUB>12</SUB> in refluxing benzene ultimately to give arylmethyl alcohols and 1,2-diaryl-1,2-ethanedione in a 1:1 ratio. In some cases, small amounts of 2,4,5-triaryl-1,3-dioxolanes are formed as minor products. Dinuclear iron complex (1,2-diphenyl-1,2-ethanedioxido)Fe<SUB>2</SUB>(CO)<SUB>7</SUB> has been isolated as an intermediate in the reaction of benzaldehyde with Fe<SUB>3</SUB>(CO)<SUB>12</SUB>. The mechanism of this redox reaction of aromatic aldehydes are discussed on the basis of the kinetic study of the reaction and also of the reactivity of the isolated dinuclear iron complex.
- 公益社団法人 日本化学会の論文
著者
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Nakanishi Saburo
Department Of Applied Chemistry College Of Engineering University Of Osaka Prefecture
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Itoh Keiji
Department Of Industrial Chemistry Osaka Prefectural College Of Technology
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Otsuji Yoshio
Department Of Applied Chemistry College Of Engineering University Of Osaka Prefecture
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