Preparation and Reactivities of (.ETA.3-1- and 2-Trimethylsiloxyallyl)Fe(CO)2NO Complexes. Intermediates Functioning as Equivalents of .BETA.- and .ALPHA.-Acyl Carbocations and Acyl Carbanions.
スポンサーリンク
概要
- 論文の詳細を見る
(η<SUP>3</SUP>-1- and 2-Trimethylsiloxyallyl)Fe(CO)<SUB>2</SUB>NO complexes were prepared by the reaction of the corresponding siloxyallylic halides with Bu<SUB>4</SUB>N[Fe(CO)<SUB>3</SUB>NO]. These complexes reacted with both of carbon nucleophiles and carbon electrophiles preferentially at the less hindered sites of the allylic ligands. In these reactions, (η<SUP>3</SUP>-1-trimethylsiloxyallyl)Fe(CO)<SUB>2</SUB>NO complexes served as synthetically equivalent synthons for both of β-acyl carbocations and j8-acyl carbanions and (η<SUP>3</SUP>-2-trimethylsiloxyallyl)Fe(CO)<SUB>2</SUB>NO complexes as both of α-acyl carbocations and α-acyl carbanions. The stereochemical courses of the reactions are described.
- 公益社団法人 日本化学会の論文
著者
-
ITOH Keiji
Department of Industrial Chemistry, Osaka Prefectural College of Technology
-
Nakanishi Saburo
Department Of Applied Chemistry College Of Engineering University Of Osaka Prefecture
-
Itoh Keiji
Department Of Industrial Chemistry Osaka Prefectural College Of Technology
-
Otsuji Yoshio
Department Of Applied Chemistry College Of Engineering University Of Osaka Prefecture
関連論文
- A Route to Functionalized (η^3-Allyl)dicarbonylnitrosyliron Complexes: Regio- and Stereoselective Acylmetallation of Allenes
- Preparation, Ligand Substitution, and Structural Stability of (η^3-Allyl)dicarbonylnitrosyliron Complexes
- Chiral Recognition with Crown Ethers Having Planar Chiral (η^4-Diene)tricarbonyliron Moieties
- A Novel Route to (η^3-Allyl)dicarbonylnitrosyliron Complexes via Transmetallation of η^3-Allyl Palladium Complexes
- Electrophilic l,2-Addition of Oxoammonium Salts to Olefins
- Neutron Diffraction Study of Liquid As-Se and As-Te Systems
- Surface Tension of Polysilanes Having Oxyethelenic Side Chanis
- Facile Routes to Ru(η^3-Allyl)(NO)(PPh_3)_2 Complexes via Hydrometallation of RuH(NO)(PPh_3)_3 to 1, 3-Butadienes and Allenes
- Chiral Discrimination in Exciplex Quenching of 2,2'-Dimethyl-1,1'-bianthryl-N,N'-Dimenthylaniline System
- Properties of Radical Cations Generated by the Pulse Radiolysis of 1, ω-Bis(diarylethenyl)alkanes. Trapping of Distonic 1,4-Radical Cation by Molecular Dioxygen
- Photooxygenation of Arylmethylsilanes via Photoinduced Electron-Transfer
- Synthesis and Properties of Polymer-Supported Cyanoaromatic Compounds
- Photocleavage of C-C Single Bond of 1,2-Bis(4-acetylphenyl)ethane Derivatives
- Thermal Rearrangement of 1-Alkenyl-2-(2',2'-diphenylethenylidene)cyclopropanes to 4-(2',2'-Diphenylethenylidene)cyclopent-1-enes
- Incorporation of CO and NO Ligands in the Reaction of Benzyl Bromides with Tetrabutylammonium Tricarbonylnitrosylferrate
- Photolysis of 2,2-Diethoxy-2,3-dihydrophenalene-1,3-dione
- Photochemistry of 9-(2-(N-substituted aminomethyl)-1-naphthyl)phenanthrenes. Intramolecular addition of amines to excited state of phenanthrene in conformationally rigid system.
- Photoinduced intramolecular cyclization of 9-(.OMEGA.-anilinoalkyl)phenanthrenes.
- Synthesis of pyrrole derivatives from 5,6-dihydro-4H-1,2-oxazones via reductive deoxygenation by use of Fe3(CO)12.
- Photochemistry of Heterocyclic Compounds. VI. The Photochemical Behavior of Phenazine in Hydroxylic Solvents
- Photochemistry of Heterocyclic Compounds. VII. The Photochemical Behavior of Phthalazine and Quinoxaline in Acidified Alcohols
- Effects of Substituents on the Formation of Acetals of 4-Substituted 1,3-Indandiones
- Preparation and Reactivities of (.ETA.3-1- and 2-Trimethylsiloxyallyl)Fe(CO)2NO Complexes. Intermediates Functioning as Equivalents of .BETA.- and .ALPHA.-Acyl Carbocations and Acyl Carbanions.
- Reaction of N-Nitroso-1,2,3,4-tetrahydroisoquinolines with Base. A New Method for the Conversion of 1,2,3,4-Tetrahydroisoquinolines into 3,4-Dihydroisoquinolines
- Redox reaction of aromatic aldehydes with Fe3(CO)12.
- The Preparation and Reactions of Benzoylnitrile Oxide from Dimethylphenacylsulfonium Bromide