Thermal dehydrogenation of cyclooctane by supported noble metal catalysts.
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概要
- 論文の詳細を見る
Under boiling and refluxing conditions, cyclooctane has been dehydrogenated to cyclooctene and molecular hydrogen selectively with carbon- and alumina-supported Pd, Ph, and Ru catalysts. The activity order among these metal catalysts was Pd>Rh>Ru. The most active carbon-supported Pd catalyst was least sensitive to the rate retardation caused by cyclooctene adsorption. Desorption of molecular hydrogen from the Pd catalyst surface was deduced to proceed rapidly after the rate-determining step.
- 公益社団法人 日本化学会の論文
著者
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Saito Yasukazu
Department Of Industrial Chemistry Faculty Of Engineering The University Of Tokyo
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Yukawa Kiyoshi
Department Of Bioengineering Nagaoka University Of Technology
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Fujii Takahiro
Department Of Astronomy The University Of Tokyo Institute Of Astronomy The University Of Tokyo
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Saito Yasukazu
Department of Industrial Chemistry, Faculty of Engineering, University of Tokyo
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Yukawa Kiyoshi
Department of Industrial Chemistry, Faculty of Engineering, University of Tokyo
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Fujii Takahiro
Department of Industrial Chemistry, Faculty of Engineering, University of Tokyo
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