A New Calix(6)arene-Based Uranophile with Phosphonate Groups as Ligands.
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概要
- 論文の詳細を見る
A new calix[6]arene-based uranophile which has six phosphonomethyl groups on the upper rim was synthesized. This compound forms a 1 : 1 complex with uranyl ion (UO<SUB>2</SUB><SUP>2+</SUP>). The stability constant was estimated to be 10<SUP>17.5</SUP> M<SUP>−1</SUP>, which is satisfactorily comparable with those for calix[6]arene-based uranophiles bearing OH or COOH groups on the lower rim.
- 公益社団法人 日本化学会の論文
著者
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Shinkai Seiji
Department Of Applied Chemistry Faculty Of Engineering Kyushu University
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Nagasaki Takeshi
Department Of Applied And Bioapplied Chemistry Graduate School Of Engineering Osaka City University
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Arimura Takashi
Department Of Industrial Chemistry Faculty Of Engineering Nagasaki University
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Shinkai Seiji
Department of Organic Synthesis, Faculty of Engineering, Kyushu University
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