Isotope Effect of Molten Thallous Nitrate in Countercurrent Electromigration
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概要
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The isotope effect of the thallous ion in the countercurrent electromigration of molten thallous nitrate has been measured at 219°C. The relative internal mobility difference between <SUP>203</SUP>Tl<SUP>+</SUP> and <SUP>205</SUP>Tl<SUP>+</SUP>, <I>ΔV</I>⁄<I>V</I><SUB>Tl</SUB>, has been determined to be 0.00035±0.00002. The mass effect μ<SUB>Tl</SUB>=(<I>ΔV</I>⁄<I>V</I><SUB>Tl</SUB>)⁄(<I>ΔM</I>⁄<I>M</I><SUB>Tl</SUB>), has been calculated to be −0.035±0.002, and this value has been compared with those of alkali nitrates previously determined.
- 公益社団法人 日本化学会の論文
著者
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Okada Isao
Department Of Chemistry Faculty Of Science And Engineering Sohia University
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Saito Nobufusa
Department of Chemistry, Faculty of Science, The University of Tokyo
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Okada Isao
Department of Chemistry, Faculty of Science, The University of Tokyo
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