Anodic Process of Thiosulfate at a Dropping Mercury Electrode
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概要
- 論文の詳細を見る
In the anodic process of thiosulfate at a dropping mercury electrode, the formation of a species Hg(S<SUB>2</SUB>O<SUB>3</SUB>)<SUB>3</SUB><SUP>4−</SUP> is considerable even in dilute solution. An equation of current-potential curve is derived with proper consideration for the formation of the species. The successive stability constant of Hg(S<SUB>2</SUB>O<SUB>3</SUB>)<SUB>3</SUB><SUP>4−</SUP> was calculated to be 3×10<SUP>2</SUP> (at 25°C and an ionic strength of 0.2) by comparing the equation with experimental results.
- 公益社団法人 日本化学会の論文
著者
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Sakuraba Shukichi
Department of Industrial Chemistry, Faculty of Engineering, Shizuoka University
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Murayama Teisuke
Department of Industrial Chemistry, Faculty of Engineering, Shizuoka University
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Sawaki Toshiko
Department of Industrial Chemistry, Faculty of Engineering, Shizuoka University
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