Kinetics of Silver(I) Ion Catalysed Oxidation of Glycine by Peroxodisulphate Ion
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概要
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The kinetics of Ag(I) ion catalysed oxidation of glycine by peroxodisulphate in aqueous medium has been studied. The reaction is found to be first order in peroxodisulphate and Ag(I) ions and almost independent of glycine concentration. The rate constant is found to decrease with the increase in the concentration of peroxodisulphate ion. Addition of neutral salts shows a retarding effect. A suitable mechanism has been proposed and a theoretical rate law has been derived to account for the results.
- 公益社団法人 日本化学会の論文
著者
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Srivastava S.
Chemical Laboratories University of Allahabad
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Srivastava S.
Chemical Laboratories, Agra College
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Chandra G.
Chemical Laboratories, Agra College
関連論文
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- Kinetics of Silver(I) Ion Catalysed Oxidation of Glycine by Peroxodisulphate Ion