Studies on the Complex Formation between Uranium and Thiomalic Acid

スポンサーリンク

概要

• 論文の詳細を見る

• Uranyl ion has been found to form an orange-yellow coloured complex with thiomalic acid. Spectrophotometric measurements reveal a composition of 1:1 as UO<SUB>2</SUB>(II) : TMA in the complex, where TMA stands for thiomalic acid. Thiomalic acid is found to behave as a bidentate ligand with UO<SUB>2</SUB>(II) in this complex. This has been concluded by potentiometric method. Magnetic susceptibility measurements, however, show an anomolous magnetic behaviour. The formation constant log<I>K</I>, at fixed pH and ionic strength as calculated from the spectrophotometric curves, comes out to be 3.0±0.1 and the corresponding free energy of formation has been calculated as －4.2±0.2 at 25°C.

• 社団法人 日本化学会の論文

著者

• Srivastava S.

  Chemical Laboratories University of Allahabad

• Mathur V.K.

  Chemical Laboratories University of Allahabad

• Nigam H.

  Chemical Laboratories University of Allahabad

• Mathur V.

  Chemical Laboratories University of Allahabad

関連論文

• Studies on the Complex Formation between Uranium and Thiomalic Acid
• Studies on the Effect of Some Anionic Detergents on the Stability of Emulsions Stabilised by Partially Flocculated Sols
• Kinetics of Silver(I) Ion Catalysed Oxidation of Glycine by Peroxodisulphate Ion

スポンサーリンク