The Trialkylborane-initiated Graft Copolymerization of Methyl Methacrylate onto Hemoglobin

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概要

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• The graft copolymerization of methyl methacrylate by trialkylborane onto hemoglobin has been studied at 37°C. In aqueous media, graft copolymers were obtained in the form of a light brown powder or granules, while no grafting occurred in organic solvents, such as cyclohexanone, <I>n</I>-hexane, tetrahydrofuran, and toluene. The presence of water seems to be essential to the grafting. The hydrogen peroxide-decomposing property of hemoglobin was well preserved in the graft copolymers so obtained. The mechanism of the initiation is discussed.

• 公益社団法人 日本化学会の論文

著者

• Iwabuchi Susumu

  Department Of Applied Chemistry Faculty Of Engineering Chiba University

• Kojima Kuniharu

  Department Of Applied Chemistry Faculty Of Engineering Chiba University

• Kojima Koichi

  Department of Applied Chemistry, Faculty of Engineering, Chiba University

• Tarumi Niro

  Institute for Medical and Dental Engineering, Tokyo Medical and Dental University

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