The Vibrational Assignment and Force Constants of Halogenomethylsilanes and Their Germanium Analogues: ClCH<SUB>2</SUB>SiH<SUB>3</SUB>, ClCH<SUB>2</SUB>SiD<SUB>3</SUB>, BrCH<SUB>2</SUB>SiH<SUB>3</SUB>, BrCH<SUB>2</SUB>SiD<SUB>3</SUB>, CICH<SUB>2</SUB>GeH<
スポンサーリンク
概要
- 論文の詳細を見る
The infrared spectra of ClCH<SUB>2</SUB>SiH<SUB>3</SUB>, ClCH<SUB>2</SUB>SiD<SUB>3</SUB>, BrCH<SUB>2</SUB>SiH<SUB>3</SUB>, BrCH<SUB>2</SUB>SiD<SUB>3</SUB>, ClCH<SUB>2</SUB>GeH<SUB>3</SUB>, and ClCH<SUB>2</SUB>GeD<SUB>3</SUB>for both the gaseous and solid states in the 250–4000 cm<SUP>−1</SUP> region have been obtained. All the fundamental vibrations except for the skeletal bending and YH<SUB>3</SUB>(–D<SUB>3</SUB>) (Y=Si, Ge) torsional vibrations have been observed and assigned. The normal vibration calculation has been carried out using a modified Urey-Bradley force field. The transferability of the force constants has also been investigated.
- 公益社団法人 日本化学会の論文
著者
-
Ohno Keiichi
Department Of Chemistry Faculty Of Science Hiroshima University
-
Murata Hiromu
Department of Chemistry, Faculty of Science, Hiroshima University
関連論文
- Cardioprotective Effect of Carvedilol against Hypoxia/Reoxygenation Injury in Cultured Rat Cardiac Myocytes
- A Novel Mechanism of Ethanol-Induced Cardiac Myocytes Injury
- Deuterium Nuclear Magnetic Resonance Study of Lipophilic Chains in the C_E_3/Decane/Water Ternary System
- Conformational Dynamics of Alkyl Chains in the Lamellar Phase of a Nonionic Surfactant C_E_3 Studied by Deuterium Nuclear Magnetic Resonance
- Protonation-induced Conformational Changes of 2-(N, N-Dimethylamino)ethanethiol. Importance of Strong N-H^+・・・S and N-H^+・・・S^- Hydrogen Bonding
- Protonation-Induced Conformational Changes of N,N,N',N'-Tetramethylethylenediamine. Importance of Strong N-H^+…N Hydrogen Bonding
- Conformational Order of the Alkyl Chain in a Nonionic Surfactant α-Dodecyl-ω-hydroxytris (oxyethylene) (C_E_3) in Water
- Specific Fragmentation of K-Shell Excited/Ionized Pyridine Derivatives Studied by Electron Impact : 2-Amino-3-methylpyridine and 3-Methylpyridine
- Remarkable Changes in the (N)CH_3 Stretching Wavenumbers of Amines on Protonation
- Two Characteristic H-bonded O-H Stretching Bands for the Compounds Containing Ether Oxygen and Hydroxyl Oxygen
- Thermal Stability of the Hydration Structure of Short-chain Poly(oxyethylene) in Carbon Tetrachloride : An Infrared Spectroscopic Observation of the Breakdown of Hydrogen Bonds
- Vibration-rotation spectrum of the coriolis-interacting band system .UPSILON.6 and .UPSILON.3 of acetonitrile-d3.
- In-Pile Calorimetric Dosimetry, (I)
- The vibrational spectra and rotational isomerism of 3-butenylsilane.
- The vibrational spectra and rotational isomerism of methylvinylsilane and allylsilane.
- The Vibrational Assignments of Propyl Bromide and Its Two Asymmetrically-Deuterated Species
- Vibrational spectra and rotational isomerism of isopropyl methyl selenide and diisopropyl selenide.
- Lattice dynamical analysis of MgO.
- Molecular Vibrations and Force Fields of Alkyl Sulfides. III. Infrared Spectra of Methyl Ethyl Sulfide
- Optically-active Vibrations and Elastic Constants of Calcite and Aragonite
- NvT- and NpT-ensemble Monte Carlo simulations of ionized matter. I. NvT-ensemble study on calcium oxide near normal melting point.
- Molecular Vibrations and Force Fields of Alkyl Sulfides. I. Dimethyl Sulfide and Its Deuterated Compounds
- Molecular Vibrations, Conformational Analyses, and Force Fields of Normal and Monodeuterated (Methylthio)methanethiol
- Molecular Vibrations and Force Fields of Alkyl Sulfides. II. Infrared Spectra of CH3S(CH2S)nCH3 (n=0–3)
- Molecular Vibrations and Force Fields of Dimethyl Selenide and Dimethyl Selenide-d6
- Molecular Vibrations and Force Fields of Alkyl Sulfides. VI. Methyl Ethyl Sulfide and Its Deuterated Compounds, and Diethyl Sulfide
- CNDO/2 calculations of MeSEt, MeS-n-Pr, MeS-n-Bu, (Et)2S, EtS-n-Pr, EtS-n-Bu, and (n-Pr)2S.
- A theoretical analysis of rotational isomerism; CNDO/2 calculations of i-PrSMe, i-PrSEt, i-Pr-S-n-Pr, and (i-Pr)2S.
- Vibrational Assignments of Ethylmethylsilane
- On the Structure of Ethyl Mercaptan
- The Molecular Vibrations and the Rotational Isomerism of (Chloromethyl)methylsilane
- Rotational Isomerism in Ethylmethylsilane
- The vibrational spectra and rotational isomerism of chloro(chloromethyl)silanes.
- Simple Mechanical Model Calculations of the Elastic Constants and Normal Frequencies of the NaNO2 Crystal
- Analysis of the short-range force including the .GAMMA.-s-type functional force.
- Molecular force field of dialkyl selenides.
- Molecular Vibrations and Force Fields of Alkyl Sulfides. IV. Infrared Spectra of Diethyl Sulfide
- Vibrational Assignments and Rotational Isomerism of Dichloroethylmethylsilane and 2,2-Dichlorobutane
- Optically-active Vibrations and Effective Charges of Calcite and Magnesite
- Vibrational spectra and rotational isomerism of 2-chloro- and 2-bromoethyl methyl sulfides.
- The Optically-active Vibration and Elastic Constant of Soda-niter
- CNDO/2 parametrizations and the applications to some organosulfur molecules: (CH2SH)2, (CH2SCH3)2, CH3SCH2SH, and CH3SCH2SCH3.
- Rotational Isomerism in Epihalogenohydrin
- The Vibrational Assignment and Force Constants of Halogenomethylsilanes and Their Germanium Analogues: ClCH2SiH3, ClCH2SiD3, BrCH2SiH3, BrCH2SiD3, CICH2GeH