Syntheses of Isoprenoids from Isoprene. III. The Dimerizations of Dimethylcyclopropanes

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概要

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• 1,1-Dimethylcyclopropane(I) was found to dimerize selectively by the action of boron trifluoride etherate. In the products, compound (III), which had been presumed, and the reaction intermediates (VII and VIII) were identified. The reaction mechanism was discussed. 1,2-Dimethylcyclopropane(VI) gave the same products.

• 公益社団法人 日本化学会の論文

著者

• Tanaka Juntaro

  Department Of Laboratory Medicine Okayama University Medical School

• Sakamoto Tadashi

  Department Of Electronics And Communication School Of Science And Engineering Waseda University

• Takabe Kunihiko

  Department Of Applied Chemistry Faculty Of Engineering Shizuoka University

• Katagiri Takao

  Department of Synthetic Chemistry, Faculty of Engineeing, Shizuoka University

• Sakamoto Tadashi

  Department of Synthetic Chemistry, Faculty of Engineering, Shizuoka University

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