The Preparation and Deamination of 1-<I>t</I>-Butyl-3-amino-, 1-<I>t</I>-Butyl-3-aminomethyl-, and 1-<I>t</I>-Butyl-2-aminomethylazetidine
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概要
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1-<I>t</I>-Butyl-3-amino, 1-<I>t</I>-butyl-3-aminomethyl-, and 1-<I>t</I>-butyl-2-aminomethylazetidine were prepared by the ammonolysis of 1-<I>t</I>-butyl-3-azetidinyl tosylate, and by the reduction of 1-<I>t</I>-butyl-3-cyano, and 1-<I>t</I>-butyl-2-cyanoazetidine respectively. In the deamination, both of the first two azetidines gave only the corresponding alcohols, 1-<I>t</I>-butyl-3-azetidinol and 1-<I>t</I>-butyl-3-hydroxymethylazetidine, while the last one was found to afford two products, 1-<I>t</I>-butyl-2-hydroxymethylazetidine and 1-<I>t</I>-butyl-3-hydroxypyrrolidine. The deamination products were identified as the corresponding acetates.
- 公益社団法人 日本化学会の論文
著者
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Chen Teng-Yueh
Institute of Chemistry, National Tsing Hua University
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Hung Mu-Huang
Institute of Chemistry, National Tsing Hua University
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Chen Po-Tau
Institute of Chemistry, National Tsing Hua University
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Ohta Masaki
Laboratory of Organic Chemistry, Tokyo Institute of Technology
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Ohta Masaki
Laboratorium für Organische Chemie, Tokio Institut für Technologies, Tokio
関連論文
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