The Surface Properties of Rutile Prepared by the Hydrolysis of Titanium Tetrachloride. I. The Heat of Immersion in Water
スポンサーリンク
概要
- 論文の詳細を見る
The surface properties of rutile prepared by hydrolyzing titanium tetrachloride have been studied by measuring the heat of immersion in water as a function of the outgassing temperature. The heat of immersion showed an extremely large value at outgassing temperatures between 300 and 400°C. However, when the rutile was calcined at 800°C, it showed a heat-of-immersion curve similar to those hitherto reported. In order to examine the phenomenon found on uncalcined rutile, the amounts of water physically and chemically adsorbed on the surface were estimated by measuring the water-vapor adsorption. We found that hydroxyl groups were formed in bulk as well as on the surface by means of the chemisorption, resulting in the formation of a hydrous structure because of the low crystallinity of the sample at temperatures below 400°C.
- 公益社団法人 日本化学会の論文
著者
-
Miura Masaji
Department of Chemistry, Faculty of Science, Hiroshima University
-
Komuro Masayoshi
Department of Chemistry, Faculty of Science, Hiroshima University
-
Iwaki Toru
Department of Chemistry, Faculty of Science, Hiroshima University
関連論文
- Grain-Size Refinements of Cu-3 mass%Ti Alloys by HDDR Treatments in Correlating with Their Electrical and Mechanical Properties
- A comparative immunohistochemistry of O^6-methylguanine-DNA methyltransferase and p53 in diffusely infiltrating astrocytomas
- Ectopic Pituitary Adenoma in the Cavernous Sinus Causing Oculomotor Nerve Paresis
- Cell Kinetics of Intracerebrally Implanted RG-C6 Tumors in Rats : Effects of Intracarotid Hyperosmolar Mannitol measured by ^3H-thymidine Autoradiography and Bromodeoxyuridine Uptake
- Quantitative analysis of neurofibrillary pathology in a general population to reappraise neuropathological criteria for senile dementia of the neurofibrillary tangle type (tangle-only dementia) : The Hisayama study
- Multiplexed Analysis of Post-PCR Fluorscence-labeled Microsatellite Alleles and Statistical Evaluation of Their Imbalance in Brain Tumors
- Characterization of the Biological Functions of a Transcription Factor, c-myc Intron Binding Protein 1 (MIBP1)^1
- Aluminum chloride does not facilitate deposition of human synthetic amyloid β1-42 peptide in the rat ventricular system of a short-term infusion model
- Active clearance of human amyloid β 1-42 peptide aggregates from the rat ventricular system
- Dynamic analysis of glioma cells : Looking into "movement phenotypes"
- Forced retraction of spinal root injury enhances activation of p38 MAPK cascade in infiltrating macrophages
- Advanced glycosylation end-products and heat shock proteins accumulate in the basophilic degeneration of the myocardium and the corpora amylacea of the glia
- Distal Sox Binding Elements of the αB-Crystallin Gene Show Lens Enhancer Activity in Transgenic Mouse Embryos
- An atypical case of sporadic Creutzfeldt-Jakob disease with Parkinson's disease
- Rosenthal fibers and glial filaments associated with hemidesmosome-like structures in perivascular astrocytes in a juvenile form of Alexander's disease
- Primary Pineal Yolk Sac Tumor : Ultrastructural and Immunohistochemical Features : Case Report
- Clinicopathological features of solitary fibrous tumor of the meninges : An immunohistochemical reappraisal of cases previously diagnosed to be fibrous meningioma or hemangiopericytoma
- Increased asymmetric pulvinar magnetic resonance imaging signals in Creutzfeldt-Jakob disease with florid plaques following a cadaveric dura mater graft
- Accumulation of MDM2 in pleomorphic xanthoastrocytomas
- Surface Plasmon Resonance Analysis for the Screening of Anti-prion Compounds
- Prion protein oligomers in Creutzfeldt-Jakob disease detected by gel-filtration centrifuge columns
- Autopsy case of autosomal recessive hereditary spastic paraplegia with reference to the muscular pathology
- Large Hypothalamic Hamartoma With Calcification and Cystic Components in an Adult : Case Report
- The effect of urea on the first and second CMC's of aqueous solutions of sodium and lithium dodecyl sulfates.
- The Surface Properties of Rutile Prepared by the Hydrolysis of Titanium Tetrachloride. I. The Heat of Immersion in Water
- Heats of Immersion of Silica-alumina in Nonaqueous Solvents
- Studies of the Basic Sites of the Silica-Alumina Surface by Means of the Adsorption of Copper(II) Complexes with 2,2′-Bipyridine
- The Nature of Acid Sites on the Surface of Silica-alumina. III. The Mechanism of the Photo-ionization of Perylene and Anthracene Adsorbed on the Surface of Silica-alumina
- Polarographic Investigation of Copper(II)-Poly(α,L-Glutamic Acid) Complex in the Helix-Coil Transition Region
- Polarographic Investigation of Biopolymers. II. Cu (II)-poly (α,L-Glutamic Acid) in the Helix-Coil Transition Region
- The Electron Spin Resonance of Binuclear Vanadyl Tartrates
- Electron Spin Resonance Studies of the Carbon Dioxide Anion Radical Adsorbed on X-Type Zeolites
- Studies of the Surface of Titanium Dioxide. I. The Effect of Reduction by Hydrogen on the Heat of Immersion in Water
- The Substitution Reaction of Ligands in Copper(II) Acetylacetonate with Pyridine on a Molecular Sieve 13X
- The Electron Spin Resonance of the Mn2+ Ion on the Surface of Magnesium Oxide
- An ESR Study of Diborane Anion Radicals in the Adsorbed State
- The Electron Spin Resonance of the Mn2+ Ion in Aqueous Surfactant Solutions
- The Second CMC of the Aqueous Solution of Sodium Dodecyl Sulfate. II. Viscosity and Density
- The Second CMC of the Aqueous Solution of Sodium Dodecyl Sulfate. III. Light-scattering
- Characterization of the Biological Functions of a Transcription Factor, c-myc Intron Binding Protein 1 (MIBP1).