Reactions of <I>N</I>-Acylaminoacetamidine with 1,3-Bifunctional Compounds
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概要
- 論文の詳細を見る
The reactions of <I>N</I>-benzoylaminoacetamidine(IIIa) and <I>N</I>-benzyloxycarbonylaminoacetamidine(IIIb) with various 1,3-bifunctional compounds were investigated. Both IIIa and IIIb were found to react with acetylacetone to produce 2-amino-3-benzoylamino-4,6-dimethylpyridine and 2-amino-3-benzyloxycarbonylamino-4,6-dimethylpyridine, respectively. On the other hand, IIIa reacted with ethyl acetoacetate or diketene to produce 2-(<I>N</I>-benzoylaminomethyl)-4-hydroxy-6-methylpyrimidine. Reaction of IIIb with malononitrile gave 1-amino-2-(<I>N</I>-benzyloxycarbonylaminoethylidene)malononitrile.
- 公益社団法人 日本化学会の論文
著者
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Ohta Masaki
Department Of Materials Science And Technology Faculty Of Science And Technology Hirosaki University
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Uchida Hiroaki
Department of Biological Chemistry, Faculty of Science, Yamagata University, 1-4-12 Kojirakawa-machi, Yamagata 990-8560, Japan
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Iwasawa Hiroyuki
Department of Chemistry, Faculty of Science, Tokyo Institute of Technology
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