The Synthesis and the Absolute Configurations of Lilac Alcohols, New Naturally Occurring Odorous Ingredients of Lilac Flower

スポンサーリンク

概要

• 論文の詳細を見る

• The conversion of racemic linalyl acetate to racemic lilac alcohols has been completed in 5 steps and four diastereoisomers of β,5-dimethyl-5-vinyl-2-tetrahydrofuranethanol were obtained. <I>d</I>-Lilac alcohols were also synthesized from <I>d</I>-linalyl acetate and confirmed to be identical with natural ones. The absolute configurations of lilac alcohol-a, -b, -c, and -d were respectively shown to be (β<I>S</I>, 2<I>S</I>, 5<I>S</I>), (β<I>R</I>, 2<I>S</I>, 5<I>S</I>), (β<I>R</I>, 2<I>R</I>, 5<I>S</I>), and (β<I>S</I>, 2<I>R</I>, 5<I>S</I>) by the chemical and physical evidences.

• 公益社団法人 日本化学会の論文

著者

• Ohno Masaji

  Basic Research Laboratories, Toray Industries, Inc.

• Hosoi Kazuo

  Basic Research Laboratories, Toray Industries, Inc.

• Wakayama Seiji

  Chemical Laboratory, Hokkaido University of Education

• Namba Satoshi

  Chemical Laboratory, Hokkaido University of Education

関連論文

• Reactions of 1-halo-1-nitroso- and 1-halo-1-nitrocycloalkanes with triphenylphosphine. A new synthesis of lactam.
• The Synthesis and Absolute Configurations of Lilac Alcohols
• Lilac Alcohol-a and -b, New Naturally Occurring Odorous Ingredients
• The Synthesis and the Absolute Configurations of Lilac Alcohols, New Naturally Occurring Odorous Ingredients of Lilac Flower
• Lilac Aldehydes
• Syntheses and the Beckmann Fission of Cyclic α-Hydroxyimino Ketones

スポンサーリンク