Reactions of 1-halo-1-nitroso- and 1-halo-1-nitrocycloalkanes with triphenylphosphine. A new synthesis of lactam.

スポンサーリンク

概要

• 論文の詳細を見る

• Reactions of 1-halo-1-nitroso- and 1-halo-1-nitrocycloalkanes with triphenylphosphine have been carried out. The Perkov reaction and Beckmann rearrangement occurred successively with the formation of lactams in high yields. The reaction of cycloalkanone oxime with halogen in the presence of triphenylphosphine also gave lactams in one step.

• 公益社団法人 日本化学会の論文

著者

• Sakai Ikuo

  Basic Research Laboratories, Toray Industries, Inc.

• Kawabe Norio

  Basic Research Laboratories, Toray Industries, Inc.

• Ohno Masaji

  Basic Research Laboratories, Toray Industries, Inc.

関連論文

• Reactions of 1-halo-1-nitroso- and 1-halo-1-nitrocycloalkanes with triphenylphosphine. A new synthesis of lactam.
• The Synthesis and Absolute Configurations of Lilac Alcohols
• Lilac Alcohol-a and -b, New Naturally Occurring Odorous Ingredients
• The Synthesis and the Absolute Configurations of Lilac Alcohols, New Naturally Occurring Odorous Ingredients of Lilac Flower
• Syntheses and the Beckmann Fission of Cyclic α-Hydroxyimino Ketones

スポンサーリンク