Synthetic Photochemistry. I. The Cycloaddition Reaction of Methyl Acetopyruvate with Olefins

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概要

• 論文の詳細を見る

• The photochemical cycloaddition reaction of methyl acetopyruvate, an unsymmetrical β-diketone, with olefins afforded the single 1 : 1 molar adducts in good yields. A ready method of the cyclization of the adducts to the β-methoxycarbonyl-<I>Δ</I><SUP>α,β</SUP>-cyclohexenones has preparative values.

• 公益社団法人 日本化学会の論文

著者

• Takeshita Hitoshi

  Department Of Emergency Medicine Osaka Mishima Emergency And Critical Care Center

• Tanno Shimaho

  Department of Chemistry, Faculty of Science, Tohoku University

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