Molecular Structure of Nortricyclene Studied by Gas Electron Diffraction

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概要

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• The molecular structure of nortricyclene (tricyclo[2.2.1.0<SUP>2,6</SUP>]heptane) has been studied by gas phase electron diffraction. The average values of the bond distances and their limits of error are: <I>r</I><SUB>g</SUB>(C–C)=1.532±0.003 Å and <I>r</I><SUB>g</SUB>(C–H)=1.11<SUB>4</SUB>±0.01<SUB>1</SUB> Å. It is further shown that <I>r</I><SUB>g</SUB>(C<SUB>3</SUB>–C<SUB>4</SUB>)=1.55<SUB>4</SUB>±0.01<SUB>3</SUB> Å, <I>r</I><SUB>g</SUB>(C<SUB>1</SUB>–C<SUB>2</SUB>)+<I>r</I><SUB>g</SUB>(C<SUB>2</SUB>–C<SUB>3</SUB>)=3.04<SUB>2</SUB>±0.01<SUB>0</SUB> Å, and ∠C<SUB>1</SUB>–C<SUB>7</SUB>–C<SUB>4</SUB>=96.9±0.5°.

• 公益社団法人 日本化学会の論文

著者

• Kuchitsu Kozo

  Department Of Chemistry Faculty Of Science The University Of Tokyo

• Fukuyama Tsutomu

  Department Of Chemistry Faculty Of Science The University Of Tokyo

• Bohn Robert

  Department of Chemistry and Institute of Materials Science, University of Connecticut

• Mizuno Kazumi

  Department of Chemistry, Faculty of Science, The University of Tokyo

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